A PDTPQx:PC61BM blend with pronounced charge-transfer absorption for organic resonant cavity photodetectors – direct arylation polymerization vs. Stille polycondensation

نویسندگان

چکیده

Because of their intriguing properties for optoelectronic applications, research on organic semiconducting polymers has steadily progressed over the past decades, yielding increasingly fine-tuned (hetero)aromatic polymer backbones. In this work, push-pull copolymer PDTPQx is synthesized, both via Stille polycondensation and direct arylation polymerization (DArP), permitting comparison two procedures. Near-infrared photodetectors (OPDs) are constructed based these different batches in combination with PC61BM, performance was investigated. From current-voltage characteristics, it clear that DArP polymer-based devices outperform those prepared from polymers, terms dark current density external quantum efficiency (EQE), therefore specific detectivity as well. The relatively high highest occupied molecular orbital energy level PDTPQx, charge-transfer absorption band observed DArP-based device, beneficial application resonant cavity photodetectors. Such OPDs PDTPQx:PC61BM (1:4) blends 180 210 nm thick bulk heterojunction active layers. EQEs 2.5% at 1016 1% 1140 achieved, full-width-at-half-maximum peak responses 44 45 nm, respectively, detectivities 2.24 × 1010 1.06 Jones.

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ژورنال

عنوان ژورنال: Dyes and Pigments

سال: 2022

ISSN: ['1873-3743', '0143-7208']

DOI: https://doi.org/10.1016/j.dyepig.2022.110130